Rate constants for the quenching of Oz(lAg) by 2,3dimethyl-2-butene and triethylamine have been determined in a discharge-flow system when NO2 is added to eliminate atomic oxygen from the system. The results indicate that in many previous determinations of rate constants for the quenching of 02(lAg)
Heavy atom quenching of the singlet delta dioxygen molecule (1Δg O2)
✍ Scribed by E.J. Corey; Ahsan U. Khan; Ha Deok-Chan
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 249 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A
The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected