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Heats of Reduction of Carbonyl Compounds

โœ Scribed by Kenneth B. Wiberga; Mark A. Murckob

Book ID
104207783
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
1006 KB
Volume
53
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

The heats of reduction of a series of compounds having C=C, C=O and C=S bonds have been ealcolated at the G2 theoretical level. The energy changes am related to the electronegativity, charge and rrdonor abihty of the substituents, andto the properties of the double bonds. @ 1997Elsevier ScienceLtd.

๐Ÿ“œ SIMILAR VOLUMES

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## Abstract Molecular mechanics (MM4) calculations on the heats of formation of aldehydes and ketones were carried out for a total of 59 compounds (10 aldehydes and 49 ketones). Optimization of the heat of formation parameters was obtained by a least squares fit to the experimentally known heats of

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Numbers of metal hydrides and organometallic hydrides are able to reduce carbonyl compounds. Every hydrides has its own characteristic feature. However, no report is given in the literature concerning the r-activities of metal hydrides of main group V other than the addition of stibine with CsC and