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Reduction of carbonyl compounds with pentacoordinate hydridosilicates

✍ Scribed by Kira, Mitsuo; Sato, Kazuhiko; Sakurai, Hideki


Book ID
120428191
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
247 KB
Volume
52
Category
Article
ISSN
0022-3263

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Heats of Reduction of Carbonyl Compounds
✍ Kenneth B. Wiberga; Mark A. Murckob πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 1006 KB

The heats of reduction of a series of compounds having C=C, C=O and C=S bonds have been ealcolated at the G2 theoretical level. The energy changes am related to the electronegativity, charge and rrdonor abihty of the substituents, andto the properties of the double bonds. @ 1997Elsevier ScienceLtd.