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Heat of formation of diphenylcyclopropenone by photoacoustic calorimetry

✍ Scribed by Grabowski, Joseph J.; Simon, John D.; Peters, Kevin S.


Book ID
125995918
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
284 KB
Volume
106
Category
Article
ISSN
0002-7863

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Enthalpy of formation of the benzoyl rad
✍ J.A.Martinho SimΓ΅es; D. Griller πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 234 KB

The energetics of the benzoyl radical have been studied by photoacoustic calorimetry. The value obtained for D[PhC (0)-H]. 371? 11 kJ mol-' (89 + 3 kcal mol-' ), agrees with an early result derived from iodination kinetic experiments and does not support a recent suggestion that the radical is reson