Lasing action has been observed following pulsed electrical discharges in mixtures of H2 and Cf20. The range of laser output covered approxlmstely 3.6 to 4.0 pm. A chain mechanism is proposed for this system, and Iasing action is attributed to H-F Cl2 -+ HCl\* + CIO.
HCl Chemical lasers with SOCl2, SO2Cl2, Cl2CNCl and ClCN
β Scribed by James R. English III; Hugh C. Gardner; Ronald W. Mitchell; James A. Merritt
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 289 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Hydrogen chloride laser emission has been produced by electric discharge initiation of mixtures of H2 and He with SOCl,, SO2Cl2, CilCNCl or CLCN. Three steps in the chain mechanisms proposed for these systems are conside:ed as possible paths for the formation of HCI?. Volume 16, number 1 CHEhI!CAL PHYSICS LETTERS
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Arrested rekxation infrared chemiluminescence studies of the H + Cl,, SCl2, !5&12, SCQ and SO&l2 reactions have been made. ihe mean fraction of vibrational fi a~ational) enem released to HCl is 0.40(0.10); 0.40(0.13); 0.38(?0.02); 0.33(?0.02) and 036 (20.02) for the series. Only the H + SC12 reactio
## Abstract Acidic rhodium(III) chloride solutions pretreated with SnCl~2~ at a ratio Sn(II) : Rh(III) = 3 are contacted with an alkylated 8βhydroxyquinoline (Kelex 100) to prepare loaded organics which subsequently are subjected to stripping with Na~2~SO~3~βHCl solutions. Rh(III) was found to be s