Hydrogen chloride laser emission has been produced by electric discharge initiation of mixtures of H2 and He with SOCl,, SO2Cl2, CilCNCl or CLCN. Three steps in the chain mechanisms proposed for these systems are conside:ed as possible paths for the formation of HCI?. Volume 16, number 1 CHEhI!CAL P
HCl chemical laser from H+Cl2O
β Scribed by M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 185 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Lasing action has been observed following pulsed electrical discharges in mixtures of H2 and Cf20. The range of laser output covered approxlmstely 3.6 to 4.0 pm. A chain mechanism is proposed for this system, and Iasing action is attributed to H-F Cl2 -+ HCl* + CIO.
π SIMILAR VOLUMES
The H + HCI potential surfaces for both reaction LhJnnel.S are calculated by a modlied dlatormcs-m-molecules method mcludmg three-center molecular Integrals Usmg the same adjustable parameters as for the FH2 system, we obtam barner heights of 5.2 kcal/mole (abstractlon) and J 4.2 kcal/moIe (exchange
## By observing mass spectrometrically the decay of H# in flames the ratio of the rate constants for the neutmfization of H30t by Cl-and the electron has been measured as 0.11 f 0.03 over the temperature range 1800-2600Β°K.
## Recefved 1 May IS70 CZV h-C1 i3sor action has been achieved by reacting chlorine atoms with hydrogen iodide in a fast (ea. 165 m/see) flow mixing device. The output consisted of the P(4). ( 5), and (6) lines of ffie 2-I vibratfotal transition.