The kinetics of anodic oxidation of chemisorbed methanol, formaldehyde, formic acid and reduced carbon dioxide on platinum have been reported in previous communications 1-3 from this laboratory. Of particular interest is the inhibitive action of chloride ions on the rate of the reactionl'3'4; this c
Halide adsorption and the anodic oxidation of chemisorbed methanol on platinum
โ Scribed by V.N. Kamath; Hira Lal
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 562 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-0728
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The limiting currents observed by Pavela for the anodic oxidation of methanol on platinixed platinum electrodes have been further interpreted. In alkaline electrolytes the limiting currents depend on the concentrations of methanol and sodium hydroxide and are caused by alow diffusion of either meth
The oxygen coverage was determined by cathodic charging curves at different potentials under the conditions of periodic, low-speed, potentiostatic current potential curves in 1 N HCIO4 with vigorous hydrogen or argon stirring between + 0"6 V and + 1"5 V. t In the case of hydrogen stirring the net cu
Abstmct-The relation between the oxide coverage of a platinum electrode and the adsorption of yttrium ions on to it has been studied in a system where both are measured without removing the electrode from the experimental solution. The oxide coverage was measured by reductive chronopotentiometry and