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Half-sandwich ruthenium complexes of pentafluorobenzenethiolato ligands

✍ Scribed by Khaled Shawakfeh; Mohammad El-khateeb; Deeb Taher; Helmar Görls; Wolfgang Weigand

Publisher
Springer
Year
2008
Tongue
English
Weight
228 KB
Volume
33
Category
Article
ISSN
0340-4285

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Olefin cyclopropanation catalysed by hal
Olefin cyclopropanation catalysed by half-sandwich ruthenium complexes
✍ Oscar Tutusaus; Sébastien Delfosse; Albert Demonceau; Alfred F Noels; Rosario Nú 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 187 KB

Ruthenium complexes of the type [RuX(Cp%)(PPh 3 ) 2 ] (X=Cl and H; Cp%=Cp, Cp\*, indenyl, and carboranyl) efficiently catalyse olefin cyclopropanation with diazoesters, and the cis/trans stereoselectivity of the resulting cyclopropanes strongly depends on the Cp% ligand. With [RuCl(Cp\*)(PAr 3 ) 2 ]