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Half-Sandwich Alkyl and Hydrido Complexes of Yttrium: Convenient Synthesis and Polymerization Catalysis of Polar Monomers

โœ Scribed by Kai C. Hultzsch; Thomas P. Spaniol; Jun Okuda

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
133 KB
Volume
38
Category
Article
ISSN
0044-8249

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Three new lanthanide (Ln)-alkylaluminium (Al) bimetallic complexes with the formula [(p-CF,CO,),Ln(p-CF,CHO2)AlR2 2THF], (Ln = Nd, Y, R = i-C4H, (i-Bu); Ln = Eu, R = C2H5(Et); THF = tetrahydrofuran) were synthesized by the reaction of Ln(CF,CO,), (Ln=Nd, Y) with HA1 (i-Bu), and of Eu(CF,CO,), with A