H Atom and H 2 Elimination from Y + C 2 H 2
β Scribed by Glendening, Eric D.
- Book ID
- 127081515
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 305 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
New high-level quantum chemical calculations have been undertaken to understand the rates and mechanisms of the reactive and associative channels for the reactants C2H2(+) + H2. The reactive channel, which produces C2H3(+) + H, has been shown to be slightly endothermic, confirming earlier calculatio
Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2