Growth kinetics of anodic zirconia films grown in alkaline solutions
β Scribed by J.S.L. Leach; C.N. Panagopoulos
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 341 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Abstractarowth
kinetics during anodizing of zirconium in sodium phosphate @H = 11.8) and sodium hydroxide (pH = 12.8) solutions show that the anodization rate, the current efficiency and the electric field are higher in the phosphate than in the hydroxide for the same growth current. This was attributed to the incorporation of phosphate anions into the growing anodic oxide.
π SIMILAR VOLUMES
The growth kinetics of thin anodic oxide films at nickel electrodes are examined in 0.1 N KOH solutions at room temperature under potentiodynamic and galvanostatic conditions. At electrodes that have been mechanically polished and cathodically reduced, growth ofthe lower oxidation state phase, fi-Ni
Anodic charging curves have been measured on Ti in Na,SO,, NaCl, NaNO,, NaH,P04, NasH PO&, Na,PO\* and NaOH solutions in the cd range 5-35 pAlcme. Formation rates are calculated in the region below Oa evolution. The results indicate the high-field approximation, with linearity between the reciproc