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Growth and crystal structure of the layered compound TlGaSe2

✍ Scribed by G. E. Delgado; A. J. Mora; F. V. Pérez; J. González

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
226 KB
Volume
42
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

The semiconducting compound TlGaSe~2~ was grown by solid state reaction technique. The crystal structure of this material was confirmed by single‐crystal X‐ray diffraction. TlGaSe~2~ crystallizes in the monoclinic system with space group C2/c (No. 15), Z = 16 and unit cell parameters a = 10.779(2) Å, b = 10.776(1) Å, c = 15.663(5) Å, β = 99.993(6)°. The structural refinement converged to R(F) = 0.0719, R(F^2^) = 0.0652 and S = 1.17. The structure consists of a three‐dimensional arrangement of distorted TlSe~8~ and GaSe~4~ polyhedrons. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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