𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Golden rule calculation of reaction product vibronic state distributions

✍ Scribed by Michael J. Berry

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
454 KB
Volume
27
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

A resonrmce decay model of bimolecular exchange reactions successfully treats product vibronic stale distributions. Product vibronic population inversions are controlled by the extent of product structural change whichoccurs as reaction energy is released.

πŸ“œ SIMILAR VOLUMES

Golden rule calculation of product vibro
Golden rule calculation of product vibronic population inversions in photodissociation and related reactions
✍ Michael J. Berry πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 English βš– 817 KB

An ultrasimple reaction dyr?amics model successfully trcat~ product vibronic state distributions in photodissociation and predissociation reactions and in collision-induced electronic-to-kibrntiod energy transfer grocesses. product vibronic populgion inversions are determinen by intrairagment dynami

Comment on β€œGeneralized golden rule trea
Comment on β€œGeneralized golden rule treatment of a photochemical solid-state reaction involving hydrogen tunneling”
✍ B. Prass; D. Stehlik πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 223 KB

The model calculations of the commented paper are based on our experimental reaction rates for the H-transfer in acridinedoped fluorene single crystals. High experimental accuracy (reported one order of magnitude too low) is crucial to realize that precise rates in a specific low-temperature region

Quantum mechanical determination of prod
Quantum mechanical determination of product state distributions in the H + D2 β†’ HD + D reaction
✍ M.S. Bowers; B.H. Choi; R.T. Poe; K.T. Tang πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 549 KB

We present three-dlmenslonal quantllm mezhamcal calculations of the product state distnbuuons rn the H + D, + HD + D reacloo The two-potential formahsm of the dutorted-wave Born approxunation 1s used with the dIstorted potential taken to be the potential between the atom and the molecule when they a

Reply to the Comment on β€œGeneralized gol
Reply to the Comment on β€œGeneralized golden rule treatment of a photochemical solid-state reaction involving hydrogen tunneling”
✍ L. Lavtchieva; Z. Smedarchina πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 279 KB

The consequences of the inaccuracy and some deliberate omissions in reporting experimental data of Prass and Stehlik in the commented paper are considered. We examine the concept that specific low-temperature data provide the most critical test for the theoretical model used. Our argument of why the