ScvcraI mcaurcments have been made by various authors on the relative contnbutmn to the Halmcra crntrsiun or the 35 state of hydrogen atolns rcsultlng frown the dlrsociatwe evcltation of El2 by electrons in the energy range 20 to 500 cV. Thcsc mcasurcmcnts, however, arc mutually Inconsistent c\cept
Calculation of Resonances and Product State Distributions for the Unimolecular Dissociation of H2S
β Scribed by Hong Zhang; Sean C. Smith
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
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Unimolecular dissociations of CFaH into (1) CF2(1AI ) + HF, (2) CF 3 + H and (3) CF2H + F were studied by means of RRKM and PST calculations on an ab initio potential energy surface. Activation energies for the three channels (1), ( 2) and (3) are 73.95, 108.20 and 130.02 kcal/mol at G2 level, respe
From the second hand in the high-resolution Fle(l) photoelectron spectrum of HzS a barrier to linearity and a bond angle have been deduced for the first excited state of H2S +.