Calculation of the vibrational envelope and bond angle in the first excited state of H2S+ from the photoelectron spectrum of H2S
β Scribed by S. Durmaz; G.H. King; R.J. Suffolk
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 202 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
From the second hand in the high-resolution Fle(l) photoelectron spectrum of HzS a barrier to linearity and a bond angle have been deduced for the first excited state of H2S +.
π SIMILAR VOLUMES
The 584 i photoelectron spectra of Hi, HD+ and Dd allow the vibrational intervals in the 2Zi states of these ions to be measured, and so the vibrational constants O, and wex, can be derived. These new
The high resolution infrared spectrum of H 2 S has been recorded on a Fourier transform spectrometer Bruker IFS 120 HR in the region of the fundamental band n 2 with an instrumental resolution of about 0.0020 cm 01 . Lines have been assigned to the n 2 bands of the isotopic species H 2 32 S, H 2 34
Excitation energies are calculated for the states arising from excitation of an outer-most valence electron of HzS, PH3 and S& by the use of the one-center expansion SCF MO and the improved virtual orbital approximations. The results are compared with experimental data.
## Abstract For Abstract see ChemInform Abstract in Full Text.
Cross sections for the photoionizztion of H= by the 3045. Line are czlcuhted for the individual vlbratioml states of the residual ion\_ The theoretical intensity agrees welI with experimental values. The resuItiq devktion from the Fran&-Condon factor is discussed.