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High Resolution Vibrational–Rotational Spectrum of H2S in the Region of the ν2Fundamental Band

✍ Scribed by O.N. Ulenikov; A.B. Malikova; M. Koivusaari; S. Alanko; R. Anttila

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
351 KB
Volume
176
Category
Article
ISSN
0022-2852

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✦ Synopsis

The high resolution infrared spectrum of H 2 S has been recorded on a Fourier transform spectrometer Bruker IFS 120 HR in the region of the fundamental band n 2 with an instrumental resolution of about 0.0020 cm 01 . Lines have been assigned to the n 2 bands of the isotopic species H 2 32 S, H 2 34 S, and H 2 33 S and in addition to the hot band 2n 2 0 n 2 of H 2 32 S. In the case of the fundamental band of H 2 32 S, 226 upper state energy levels with J max Å 17 were obtained and fitted with a standard deviation of 9.96 1 10 05 cm 01 . For H 2 34 S, 126 energy levels with J max Å 14 were obtained, and for H 2 33 S, 57 lines could be assigned.

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