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Gold-Catalyzed Synthesis of Bicyclo[3.2.0]heptenes via a Formal [3+2]/[2+2]-Annulation of Allylsilane with 4-Methoxybut-2-yn-1-ols

✍ Scribed by Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 214 KB
Volume: 352
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201000201

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✦ Synopsis

Abstract

This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.

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