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Gold-Catalyzed Cycloisomerization Reactions of 2-Tosylaminophenylprop-1-yn-3-ols as a Versatile Approach for Indole Synthesis

✍ Scribed by Prasath Kothandaraman; Weidong Rao; Shi Jia Foo; Philip Wai Hong Chan

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
306 KB
Volume
122
Category
Article
ISSN
0044-8249

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✍ Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 214 KB 👁 1 views

## Abstract This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.