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Intermolecular and Selective Synthesis of 2,4,5-Trisubstituted Oxazoles by a Gold-Catalyzed Formal [3+2] Cycloaddition

✍ Scribed by Dr. Paul W. Davies; Alex Cremonesi; Dr. Lidia Dumitrescu


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
423 KB
Volume
123
Category
Article
ISSN
0044-8249

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Gold-Catalyzed Synthesis of Bicyclo[3.2.
✍ Chun-Yao Yang; Chiou-Dong Wang; Shu-Fan Tian; Rai-Shung Liu πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 214 KB

## Abstract This work reports the novel gold‐catalyzed [3+2]/[2+2]‐annulation of allylsilane with 4‐methoxybut‐2‐yn‐1‐ols that yields highly strained bicyclo[3.2.0]heptene products efficiently and stereoselectively.