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Gold carbene complexes as intermediates in the α-addition of amines to isocyanides

✍ Scribed by John E. Parks; Alan L. Balch


Book ID
108347043
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
247 KB
Volume
57
Category
Article
ISSN
0022-328X

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N-Heterocyclic Carbene–Palladium Complex
✍ Shuzhan Zheng; Xingao Peng; Jianming Liu; Wei Sun; Chungu Xia 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 69 KB

## Abstract A highly efficient oxidative carbonylation reaction of amines to ureas was developed making use of carbene–palladium complexes in the absence of any promoter. Both aliphatic amines and aromatic amines were transformed in good to excellent yields to the expected ureas.