Glycosyl thioimidates in a highly convergent one-pot strategy for oligosaccharide synthesis
β Scribed by Papapida Pornsuriyasak; Alexei V. Demchenko
- Book ID
- 108283868
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 325 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0957-4166
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π SIMILAR VOLUMES
One-pot glycosylations of glycosyl bromides and phenylthio glycosides with various dihydroxyl glycosyl acceptors have been examined to provide the corresponding branched trisaccharides.
We have developed a novel glycosylation strategy in which a tritylated thioglycoside can act as a glycosyl donor and acceptor. In combination with previously reported chemoselective glyeosylations, this feature enables highly convergent assembly of ofigosacchaddes
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