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Trityl ethers in oligosaccharide synthesis: A novel strategy for the convergent assembly of oligosaccharides
β Scribed by Geert-Jan Boons; Simeon Bowers; Diane M. Coe
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 248 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
We have developed a novel glycosylation strategy in which a tritylated thioglycoside can act as a glycosyl donor and acceptor. In combination with previously reported chemoselective glyeosylations, this feature enables highly convergent assembly of ofigosacchaddes
π SIMILAR VOLUMES
A novel glycosylation strategy has been developed whereby a silyl protected thioglycoside can act as both glycosyl donor and acceptor. Taking advantage of a two directional approach in combination with previously reported orthogonal glycosylations, enables highly convergent and versatile assembly of
Novel Regioselective Glycosylations for the Convergent and Chemoselective Assembly of Oligosaccharides. -The novel chemoselective glycosylation strategy, which is based on the differences in reactivity between hydroxyl groups of a glycosyl donor such as (I) and an acceptor, e.g. (II), provides a pr