A moment theory analysis is performed on the optical absorption spectra of surplus electrons localized in various media. The deduced attnbutes of the excess particle are compared with those obtained by a perturbation treatment of the exact ground state solution of a currently popular model potential
Geometrical structure of solvated electrons
โ Scribed by Larry Kevan
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 806 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0146-5724
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The theory of timedependent transient spectra of solvated electrons is developed. It is shown that the evolution of the spectral line centre reproduces the time dependence of the classical correlation function of the random process of electronic energy level fluctuations. The results of this invest
Using the techniques of pulse radiolysis a short-lived transient absorbing species (Xrnax = 1500 run] has been observed in liquid hydrocarbons at 193%. This absorption has been assigned to a trapped or sofvated electron and a&olute reaction rates have been obtained for reactions of sohated electrons