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Generation of reactive aryl radical intermediates in the reductive photodehalogenation of itraconazole

✍ Scribed by Nardi, Giacomo ;Marin, M. Luisa ;de Souza, Pierre A. ;Lhiaubet-Vallet, Virginie ;Miranda, Miguel A.

Book ID
126859766
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
338 KB
Volume
4
Category
Article
ISSN
2046-2069

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## Abstract The photochemistry of 2,6‐dimethyl‐4‐chlorophenol (**6**) has been studied in methanol and trifluoroethanol (TFE) through product studies and transient absorption spectroscopy. Chloride loss from triplet **6** gave triplet hydroxyphenyl cation **14**, which equilibrated with triplet oxo