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Generation and Absolute Reactivity of an Aryl Enol Radical Cation in Solution

✍ Scribed by Schepp, Norman P.

Book ID
121859821
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
110 KB
Volume
69
Category
Article
ISSN
0022-3263

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Lactone enol cation-radicals: gas-phase
Lactone enol cation-radicals: gas-phase generation, structure, energetics, and reactivity of the ionized enol of butane-4-lactone
✍ František Tureček; Shetty Vivekananda; Martin Sadílek; Miroslav Polášek 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 704 KB

## Abstract The cation‐radical of 2‐hydroxyoxol‐2‐ene (**1**^+·^) represents the first lactone enol ion whose structure and gas‐phase ion chemistry have been studied by experiment and theory. Ion **1**^+·^ was generated by the McLafferty rearrangement in ionized 2‐acetylbutane‐4‐lactone and charact