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Generation and Study of the Reactivity of α-Ammonium Distonic Radical Cations in Solution

✍ Scribed by Rios, Luz Amalia; Dolbier,, William R.; Paredes, Rodrigo; Lusztyk, Janusz; Ingold, K. U.; Jonsson, Mats


Book ID
121237426
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
206 KB
Volume
118
Category
Article
ISSN
0002-7863

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The key intermediates in the fragmentation of metastable methyl and ethyl benzoate radical cations are a-and j-distonic isomers of the molecular ions. The a-distonic isomers are also formed by fragmentation of longer chain alkyl benzoates, but may not be long-lived, stable species. Rearrangement of