The reactive nature of α-ammonium distonic radical cations

ChemInform Abstract: Structure and React

ChemInform Abstract: Structure and Reactivity of Selected Distonic Radical Cations

✍ R. L. SMITH; P. K. CHOU; H. I. KENTTAMAA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 2 views

α-Distonic ions as transient species in

α-Distonic ions as transient species in the reactions of metastable alkyl benzoate radical cations

✍ Henri Edouard Audier; Arielle Milliet; Georges Sozzi; Steen Hammerum 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB

The key intermediates in the fragmentation of metastable methyl and ethyl benzoate radical cations are a-and j-distonic isomers of the molecular ions. The a-distonic isomers are also formed by fragmentation of longer chain alkyl benzoates, but may not be long-lived, stable species. Rearrangement of

Deprotonation of α-distonic ions. Proton

Deprotonation of α-distonic ions. Proton affinities of the α-radicals

✍ H.E. Audier; J. Fossey; P. Mourgues; D. Leblanc; S. Hammerum 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 645 KB

The proton affinity at the heteroatom PA, of four o-radicals ('CH,OH, CH3'CHOH, 'CH20CH3 and 'CHrNH,) was measured by studying the deprotonation of the corresponding ol-distonic ions in the cell of a FITCR spectrometer. This method can only be used for cu-distonic ions which are more stable than the

Role of distonic dimer radical cations i

Role of distonic dimer radical cations in the radiation-induced polymerisation of vinyl ethers

✍ Sergej Naumov; Igor Janovský; Wolfgang Knolle; Reiner Mehnert 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 230 KB

The experimental low-temperature EPR results and the quantum chemical calculations suggest that dimer radical cations of cyclic and aliphatic vinyl ethers (VE) plays a key role in starting of radiation-induced polymerisation. The main species observed at high 2,3-dihydrofuran (DHF), 2,3-dihydropyran

Understanding Reactivity Patterns of the

Understanding Reactivity Patterns of the Dialkylaniline Radical Cation.

✍ Micha Kirchgessner; Kesavapillai Sreenath; Karical R. Gopidas 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 22 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Reactivity of Triarylphosphine Peroxyl R

Reactivity of Triarylphosphine Peroxyl Radical Cations Generated Through the Reaction of Triarylphosphine Radical Cations with Oxygen.

✍ Sachiko Tojo; Shinro Yasui; Mamoru Fujitsuka; Tetsuro Majima 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 11 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.