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Aryl Cation and Carbene Intermediates in the Photodehalogenation of Chlorophenols.

✍ Scribed by Ilse Manet; Sandra Monti; Maurizio Fagnoni; Stefano Protti; Angelo Albini

Publisher
John Wiley and Sons
Year
2006
Weight
19 KB
Volume
37
Category
Article
ISSN
0931-7597

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Aryl Cation and Carbene Intermediates in
Aryl Cation and Carbene Intermediates in the Photodehalogenation of Chlorophenols
✍ Ilse Manet; Sandra Monti; Maurizio Fagnoni; Stefano Protti; Angelo Albini πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 495 KB πŸ‘ 1 views

## Abstract The photochemistry of 2,6‐dimethyl‐4‐chlorophenol (**6**) has been studied in methanol and trifluoroethanol (TFE) through product studies and transient absorption spectroscopy. Chloride loss from triplet **6** gave triplet hydroxyphenyl cation **14**, which equilibrated with triplet oxo