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(Z)-1-Aryl-1-haloalkenes as Intermediates in the Vilsmeier Haloformylation of Aryl Ketones.

โœ Scribed by Annamaria Lilienkampf; Mikael P. Johansson; Kristiina Waehaelae


Publisher
John Wiley and Sons
Year
2004
Weight
107 KB
Volume
35
Category
Article
ISSN
0931-7597

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Abstract

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Short communication: An alternative and
โœ Taichi Nakano; Kenji Kawai; Takanori Endoh; Shintaro Osada; Takashi Miyamoto ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 104 KB ๐Ÿ‘ 1 views

The Pd(dba) 2 -catalyzed reaction of Z-1-aryl-1-(tributylstannyl)-2-(trimethylsilyl)ethenes with allyl bromide in the presence of copper(I) iodide is reported for the first time. The reaction in the presence of 0.5 mol% Pd(dba) 2 and 8 mol% CuI in dimethylformamide takes place at room temperature to