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An Alternative and Effective Catalyst in the Stereospecific Reaction of Z-1-Aryl-1-stannyl-2-silylethenes with Allyl Bromide.

✍ Scribed by Taichi Nakano; Kenji Kawai; Takanori Endoh; Shintaro Osada; Takashi Miyamoto

Publisher
John Wiley and Sons
Year
2006
Weight
15 KB
Volume
37
Category
Article
ISSN
0931-7597

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Short communication: An alternative and
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## Abstract Stereospecific synthesis of a family of novel (__E__)‐2‐aryl‐1‐silylalka‐1,4‐dienes or (__E__)‐4‐aryl‐5‐silylpenta‐1,2,4‐trienes via a cross‐coupling of (__Z__)‐silyl(stannyl)ethenes with allyl halides or propargyl bromide is described. In the reaction with allyl bromide, either a Pd(db