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General and Highly Efficient Iron-Catalyzed Hydrogenation of Aldehydes, Ketones, and α,β-Unsaturated Aldehydes

✍ Scribed by Fleischer, Steffen; Zhou, Shaolin; Junge, Kathrin; Beller, Matthias


Book ID
120088476
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
812 KB
Volume
52
Category
Article
ISSN
0044-8249

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Efficient rhodium-catalyzed hydrogenatio
✍ Mark J. Burk; T.Gregory P. Harper; Jeffrey R. Lee; Christopher Kalberg 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 344 KB

A cationic rhodium(l) catalyst bearing the air-stable and crystalline diphosphine 1 ,l'-bis-(diisopropylphosphino)ferrocene (1, DiiFc) allows the hydrogenation of aldehydes and ketones under mild conditions. The preparation of alcohols through reduction of the carbon-oxygen double bond of aldehydes