Efficient rhodium-catalyzed hydrogenatio
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Mark J. Burk; T.Gregory P. Harper; Jeffrey R. Lee; Christopher Kalberg
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Article
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1994
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Elsevier Science
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French
⚖ 344 KB
A cationic rhodium(l) catalyst bearing the air-stable and crystalline diphosphine 1 ,l'-bis-(diisopropylphosphino)ferrocene (1, DiiFc) allows the hydrogenation of aldehydes and ketones under mild conditions. The preparation of alcohols through reduction of the carbon-oxygen double bond of aldehydes