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Homogeneous hydrogenation of α,β-unsaturated aldehydes catalyzed by ruthenium and osmium complexes

✍ Scribed by Roberto A. Sánchez-Delgado; Antida Andriollo; Norma Valencia


Publisher
Elsevier Science
Year
1984
Weight
237 KB
Volume
24
Category
Article
ISSN
0304-5102

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Homogeneous catalytic transfer-hydrogena
✍ Yoel Sasson; Jochanan Blum 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 185 KB

Dichlorotris(triphenylphosphine)ruthenium (II), RuC12(PPh3)3, is well known for its ability to catalyze hydrogen transfer in several organic reactions l-10 . We now wish to report the application of this effect to the selective transfer-hydrogenation of a&unsaturated carbonyl compounds. A mixture of