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The Darzens condensation of α,β-unsaturated aldehydes and ketones

✍ Scribed by Marie E. Krafft; Steven J.R. Twiddle; John W. Cran


Book ID
104098835
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
618 KB
Volume
52
Category
Article
ISSN
0040-4039

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Regioselectivity in the cross condensati
✍ Andrea Pochini; Giuseppe Puglia; Rocco Ungaro 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 166 KB

Kinetic selectivity" in the cross condensation of a,B-unsaturated aldehydes and methyl ketones are obtained using 2,4,6-trimethylphenoxymagnesium bromide (2,4,6-TMPOMgBr) in benzene as catalyst. Recent observations made by several authors that organic reactions are subjected to a fundamental cation