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Geminate recombination and relaxation of molecular bromine

✍ Scribed by N.Alan Abul-Haj; David F. Kelley

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
602 KB
Volume
119
Category
Article
ISSN
0009-2614

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✦ Synopsis

Puxwecond absorption spectra and Line&s of room lempsmture Br,/CCI. solutions rollowing 532 nm exciisuon are prcscnted Gtcirauon ar 532 nm resulrs HI prcdawctntian followed by rapid recombinaLion into Ihe ground or clec~ronically exclied A'I-I,, ond A'311,, s~atcs Approxxmnrely 60% of the molecules are Irapped in thr A'31'T,, slate. which has a ~oc~rn lcmperature lifetime ol = 5.5 ns The specrra also mdlcale Ihat wbrationai relaxation in ihc ground-state mamfold is complete rs~Ilhlrl = 140 ps.

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## Abstract The recombination of bromine atoms at room temperature has been studied by flash photolysis in the range of 1–100 atm of the inert diluent He, leading to a value for the third‐order rate constant of (1.5 Β± 0.2) Γ— 10^15^ cm^6^/mol^2^.sec. In the presence of NO the recombination is consid