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GC/MS analysis of chlorinated paraffins with negative ion chemical ionization

✍ Scribed by Müller, Markus D. ;Schmid, Peter P.

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
364 KB
Volume
7
Category
Article
ISSN
0935-6304

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✦ Synopsis

Although chlorinated paraffins (CP) are produced in large amounts (300000 tonnes per year), little is known about their occurrence in the environment due to the lack of specific and sensitive analytical methods. The present paper describes the GC/MS analysis of different CP's using capillary gas chromatography with on-column injection and negative ion chemical ionization (NCI) mass spectrometry. Chromatographic resolution of groups of isomers and homologues was obtained. The chromatograms and mass spectra are discussed. The suitability of this method for trace analysis of a CP sample using multiple ion detection (MID) is described.

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