✦ LIBER ✦

Gas-phase transuranium chemistry: reactions of actinide ions with alcohols and thiols

✍ Scribed by Gibson, John K.

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 168 KB
Volume: 34
Category: Article
ISSN: 1076-5174
DOI: 10.1002/(sici)1096-9888(199911)34:11<1166::aid-jms876>3.0.co;2-z

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✦ Synopsis

The laser ablation with prompt reaction and detection method was employed to provide a survey of some gasphase reactions of actinide (M = U, Np, Pu and Am) and lanthanide (M = Tb and Tm) ions, M Y and MO 1,2 Y , with alcohols, thiols and ethers. Particular attention was given the changing behavior in progressing across the actinide series beyond uranium. With alcohols, ROH, major products included hydroxides and alkoxides, M(OH) 1,2 Y , M(OR) 1,2 Y , MO(OH) Y and MO(OR) Y ; these products are presumed to have resulted from RO-H and R-OH bond cleavage by ablated M Y and MO Y .

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