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Gas-phase structures of trans-disubstituted SF6 derivatives: CF3SF4CF3, CF3SF4Cl and CF3SF4CH3

✍ Scribed by Kohrshed Alam; Jean'ne M. Shreeve; Hans Georg Mack; Heinz Oberhammer

Book ID
107803070
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
357 KB
Volume
178
Category
Article
ISSN
0022-2860

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Reactions of CF3SF3ξ—»NCF3 with nucleophil
Reactions of CF3SF3ξ—»NCF3 with nucleophiles and the preparation of CF3SF4N(F)Rf (Rf = CF3,C2F5)
✍ Shin-Liang Yu; Jean'ne M. Shreeve πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 464 KB

The new compounds, CF3SF(0)=NCF3 and CF3SF(=NCH3)=NCF3, result from nucleophilic displacement reactions of CF3SF3=NCF3 with water and methylamine, respectively. Higher yields of the di-imine are obtained when CH3N(Si(CH3)3)2 is substituted for CH3NH2. Stable fluoroamines, CF3SF4N(F)Rf (Rf = CF3, C2F