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Gas phase reactivity of cation radicals and protonated species from isomeric C4H8S thioethers

✍ Scribed by C. Paradisi; A. Visentini; P. Traldi


Book ID
112129230
Publisher
Journal of Heterocyclic Chemistry
Year
1989
Tongue
English
Weight
267 KB
Volume
26
Category
Article
ISSN
0022-152X

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Lactone enol cation-radicals: gas-phase
✍ František Tureček; Shetty Vivekananda; Martin Sadílek; Miroslav Polášek 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 704 KB

## Abstract The cation‐radical of 2‐hydroxyoxol‐2‐ene (**1**^+·^) represents the first lactone enol ion whose structure and gas‐phase ion chemistry have been studied by experiment and theory. Ion **1**^+·^ was generated by the McLafferty rearrangement in ionized 2‐acetylbutane‐4‐lactone and charact