The structures of gas-phase [C4H601+' radical cations and their daughter ions of composition [C2H20]+' and [C,H,]+' were investigated by using collisionally activated dissociation, metastable ion measurement, kinetic energy release and collisional ionization tandem mass spectrometric techniques. Ele
The gas phase ion chemistry of the acetyl cation and isomeric [C2H3O]+ ions. On the structure of the [C2H3O]+ daughter ions generated from the enol of acetone radical cation
โ Scribed by Peter C. Burgers; John L. Holmes; Jan E. Szulejko; Alexander A. Mommers; Johan K. Terlouw
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 931 KB
- Volume
- 18
- Category
- Article
- ISSN
- 1076-5174
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Characterization of [C,H,O]+ ions in the gas phase using theu+collisional activation 2pectra shows thTt the tour C3H&O komers CH,=C(CH,)E=O, CH,=CHCH,C=O, CH,CH=CHC=O and p C = O are stable fyr z= lo-' s. It is conciuded further from the characteristic shapes for the unimolecuiar !os of CO from C3H5