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Ion/Molecule Reactions of Cation Radicals Formed from Protonated Polypeptides via Gas-Phase Ion/Ion Electron Transfer

✍ Scribed by Xia, Yu; Chrisman, Paul A.; Pitteri, Sharon J.; Erickson, David E.; McLuckey, Scott A.


Book ID
127091013
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
328 KB
Volume
128
Category
Article
ISSN
0002-7863

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Unimolecular gas-phase reactions of the
✍ DorothΓ©e Berthomieu; Jeanine Tortajada; Jean-Pierre Morizur; Henri-Edouard Audie πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 588 KB

The reactions of metastable decomposing methyl acetoacetate (a mixture of keto and enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [ M -CO] +', IM -CHzO