The complexes {[Cu(3,3 0 -azpy were synthesized. The crystal structures show that one-dimensional helical chains [Cu(3,3 0 -azpy) 3 (H 2 O) 2 ] n 2nรพ are formed and the helical chains are organized into three-dimensional molecule networks by hydrogen bonding and p-p stacking interactions in 1 and 2
Gas-Phase Reactions of Catecholate and Related Anions with BF3 and SiF4
โ Scribed by Taylor, W. S.; Babcock, Lucia M.
- Book ID
- 127205617
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 831 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Many gas-phase anions react with carbonyl sulfide by sulfur atom transfer to form RS ions. The properties of HzNS-, formed in this way from HzN-and OCS, are described.
## Reaclrons of SlF2 rndlcnls have been sludled m a fast-flow syslem Rate conskm~s at 295 K of (47&03)~10-'~ cm' molecule-' s-' for the reactIon of SIFT + F2. and (5 1 +\_O 6)X1O-'3 cm' molecule-' s -' for SIF, + Cl, were obtamed No reacuon was observed with O2 and Hz SIF, wz detected by laser-Ind
Gas-phase reactions of benzyl and methoxide anions with alkyl formate and other esters were compared using Fourier transform io cyclotron resonance spectroscopy. Although these anions have similar basicities, in many cases the reaction pathways differ.