Gas-Phase Reaction Pathways from SiH 4 to Si 2 H 6 , Si 2 H 4 and Si 2 H 2 : A Theoretical Study
โ Scribed by Hu, Shao-Wen; Wang, Yi; Wang, Xiang-Yun; Chu, Ti-Wei; Liu, Xin-Qi
- Book ID
- 125929100
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 225 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Local pseudopotential calculations have been performed for the ground state of disilane as well as for the lowest singlet and triplet states of disilene and silylsilylene. Comparison with all-electron calculations shows good agreement for geometries and relative stabilities.
Reaction rate constartls of SiHI(%'At) have been directly measured for the first time using the laser photolysis-laser-induced fluorescence method. The preparation of SiH: radical in the laser photolysis (193 m-n) or phenylsilane and the concentration of the radiczd is demonstrated by a dye laser at