Gas-Phase Pyrolysis of 1,3,3-Trinitroazetidine: Shock Tube Kinetics
โ Scribed by Zhang, Yi-Xue; Bauer, S. H.
- Book ID
- 126062866
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 262 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
The gas-phase pyrolysis of 3-chloroquadricyclane [1] was investigated over the temperature range 513-550 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-chloroquadricyclane to 7-chloronorbornadiene (E ฯญ 39.63 ฯฎ 1.40 kcal/mole, a 7-chloronorbornadiene rearranges (623-660
I .3-Butadiene ( I .3-C4H6) was heated behind reflected shock waves over the temperature range of 1200-I700 K and the total density range of 1.3 X 10-5-2.9 X lo-' mol/cm' Reaction products were analyzed by gas-chromatography. The concentration change of I .3-butadiene was Followed by U V kinetic abs
The gas-phase pyrolysis of 3-t-butoxyquadricyclane [ 1 ] was investigated over the temperature range 51 1-542 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-fbutoxyquadricyclane to 7-f-butoxynorbornadiene (Ea = 38.49 5 0.85 kcalhole. log A = 15.44 ? 0.35). 7-t-butoxynor