Homogeneous pyrolysis kinetics of ethyl 3-hydroxy-3-methylbutanoate in the gas phase
โ Scribed by Dominguez, Rosa M. ;Chuchani, Gabriel ;Quijano, Jairo ;Orozco, Luz Janeth ;Restrepo, Iliana
- Book ID
- 112689671
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 217 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0133-1736
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๐ SIMILAR VOLUMES
The gas-phase pyrolysis of 3-chloroquadricyclane [1] was investigated over the temperature range 513-550 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-chloroquadricyclane to 7-chloronorbornadiene (E ฯญ 39.63 ฯฎ 1.40 kcal/mole, a 7-chloronorbornadiene rearranges (623-660
The gas-phase pyrolysis of 3-t-butoxyquadricyclane [ 1 ] was investigated over the temperature range 51 1-542 K at one atm in helium. The initial pyrolysis step is the isomerization of 3-fbutoxyquadricyclane to 7-f-butoxynorbornadiene (Ea = 38.49 5 0.85 kcalhole. log A = 15.44 ? 0.35). 7-t-butoxynor