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Gas phase photodissociation spectrum of Cl−2

✍ Scribed by S.A. Sullivan; B.S. Freiser; J.L. Beauchamp

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
385 KB
Volume
48
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rcccwcd 15 I cbruary 1977

Photoinduced rcxtions of Cl: have been cx,nnincd in tho gas ph.rsc using ion cyclotron wsonrlncc tcchniqucs. The molcc-u1Jr ion is obwrvcd LO undergo phorodissocl.rtlon in prcfcrcncc to photodctnchrncnt.

The photoclis\ocidtion opcctrum CY-hIbit\ one broad peak in the rc.~vcIcnglh rcclon 220-700 nm, wltb a m.lGnum hma, = 350 t 10 nm, which can be .ittribulcd t~thc~X+u-*~X; transition, Tlw, rpcctrum IS compared to nbsorptwn spectra of Cl; obtained in solid state cnvironincnts.

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