The gas-phase clustering reactions of SF~, SF 6 and F-ions with SF 6 were measured using a high-pressure mass spectrometer. The bond energies of SFs--(SF6) 1 and SF6(SF6) 1 were estimated to be ~< 2.3 kcal/mol. The bond energies of F-(SF6) , with n = 1 and 2 were determined to be 5.4 and = 4.1 kcal/
✦ LIBER ✦
Gas-Phase Chemistry of the Sulfur Hexafluoride Fragment Ions SF n + ( n = 0−5) and SF n 2+ ( n = 2, 4). Ab Initio Thermochemistry of Novel Reactions of S +• and SF +
✍ Scribed by Sparrapan, Regina; Mendes, Maria Anita; Ferreira, Isabel P. P.; Eberlin, Marcos N.; Santos, Cristiano; Nogueira, José Carlos
- Book ID
- 126944383
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 221 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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