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Gas-phase molecular structure of sulfur tetrafluoride methylimide, CH3N:SF4. An NMR, electron diffraction, microwave, and ab initio study

✍ Scribed by Guenther, Horst.; Oberhammer, Heinz.; Mews, Ruediger.; Stahl, Ingo.


Book ID
126086869
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
486 KB
Volume
21
Category
Article
ISSN
0020-1669

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High level ab initio MO calculations at the G3(MP2) level of theory were employed to study the molecular structures of SF 2 , FSSF 3 , and SSF 4 , as well as the dimerization of gaseous SF 2 to FSSF 3 and the isomerization of FSSF 3 to SSF 4 . The dimerization of SF 2 was calculated to be an exother