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Gas-phase association reactions of trimethylsilylium ((CH3)3Si+) with organic bases

✍ Scribed by John A. Stone

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 264 KB
Volume: 16
Category: Article
ISSN: 0277-7037
DOI: 10.1002/(sici)1098-2787(1997)16:1<25::aid-mas2>3.0.co;2-c

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✦ Synopsis

This article is a review of the gas-phase association reactions and neutralization. The ease of experimentation with R 3 Si / in the gas phase is contrasted with the difficulty of its recognition of (CH 3 ) 3 Si / with organic bases. The reactions are considered under the headings of the three pressure regimes under which and observation in the condensed phase. ᭧ 1997 John Wiley & Sons, Inc., Mass Spectrom Rev 16(1), 25-49, 1997 they are studied. ICR and FTICR studies, carried out at pressures of 10 05 and lower, allow insights into the stabilizations, collisional and radiative, and decompositions of the nascent adducts. At pressures around 2 Torr, chemical ionization studies is a stable tricoordinate silicon-centered ion. A significant

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