Gas-phase acidities of diols
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Catherine A. Crowder; John E. Bartmess
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Article
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1993
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Elsevier Science
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English
โ 454 KB
The gas-phase acidities of several ฮฑ, ฯ-alkanediols were measured with the equilibrium method in an ion cyclotron resonance spectrometer. The values obtained imply cyclization of the structures via an intramolecular hydrogen bond. The results are in quantitative disagreement with those obtained by t