The gas-phase equilibrium reaction between fluorobenzene and chlorobenzene and their conjugate bases was studied by Fourier transform ion cyclotron resonance spectrometry in order to reconcile conflicting experimental results obtained using different techniques. The results of a large number of meas
Relative gas-phase acidities of some fluoroalcohols
โ Scribed by J.H.J. Dawson; K.R. Jennings
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 437 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0020-7381
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
AM1 and ab initio calculations were performed for molecular glucopyranose and its alkoxy anions. Minimum energy conformers were found for both the a-and b-anomers of molecular glucose and each of the corresponding deprotonated species. Cooperative hydrogen bonding towards the charge site was observe
The gas-phase acidities of several ฮฑ, ฯ-alkanediols were measured with the equilibrium method in an ion cyclotron resonance spectrometer. The values obtained imply cyclization of the structures via an intramolecular hydrogen bond. The results are in quantitative disagreement with those obtained by t